Product ID:TURCO LIQUID SMUT-GO NC
MSDS Date:08/15/1995
FSC:6850
NIIN:01-341-7979
Status Code:A
MSDS Number: CKJGR

TURCO PRODUCTS, INC. DIVISION OF ELF ATOCHEM NORTH AMERICA

2375 STATE ROAD
CORNWELLS HEIGHTS, PA 19020
US

Emergency Phone: 202-483-7616

Info Phone: 215-245-3128

Preparer: NOT PROVIDED

Cage: TO253

TURCO PRODUCTS, INC. DIVISION OF ELF ATOCHEM NORTH AMERICA

CORNWELLS HEIGHTS, PA 19020 US

Telephone: 215-245-3128

Cage: TO253

FERRIC SULFATE (SARA III)

CAS: 10028-22-5

RTECS: NO8505000

OSHA PEL 1 MG/M3 (FE)

ACGIH TLV: 1 MG/M3 (FE)

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

SODIUM BIFLUORIDE (SARA III)

CAS: 1333-83-1

RTECS: WB0350010

OSHA PEL 2.5 PPM (F)

ACGIH TLV: 2.5 PPM (F)

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

NITRIC ACID (SARA III)

CAS: 7697-37-2

RTECS: QU5775000

OSHA PEL 2 PPM

ACGIH TLV: 2 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

FERROUS SULFATE (SARA III)

CAS: 7720-78-7

RTECS: NO8500000

OSHA PEL NOT PROVIDED

ACGIH TLV: NOT PROVIDED

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

WATER

CAS: 7732-18-5

RTECS: ZC0110000

LD50 LC50 Mixture:NOT PROVIDED
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EFFECTS OF OVEREXPOSURE: CONTACT OF
PRODUCT SOLUTION OR MIST WITH EYES MAY CAUSE SEVERE IRRITATION,
POSSIBLE CHEMICAL BURNS, POSSIBLE SEVERE TISSUE DAMAGE OR
DESTRUCTION, POSSIBLE BLINDNESS. SKIN: WIL L CAUSE SEVERE
IRRITATION, POSSIBLE CHEMICAL BURNS WHICH MAYNOT BE IMMEDIATELY
OBVIOUS OR PAINFUL, POSSIBLE SEVERE TISSUE DAMAGE, POSSIBLY LEADING
TO PERMANENT DESTRUCTION OF SURROUNDING TISSUE. INHAL ATION: MAY
CAUSE SEVERE IRRITATION, POSSIBLE DAMAGE TO UPPER RESPIRATORY
TRACT. INGESTION: SEVERE IRRITATION TO GASTROINTESTINAL TRACT,
POSSIBLE TISSUE DAMAGE, MAY BE HARMFUL OR FATAL IF SWALLOWED. TO
XIC EFFECTS MAY NOT APPEAR IMMEDIATELY.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:CONTACT OF PRODUCT SOLUTION OR MIST WITH EYES
MAY CAUSE SEVERE IRRITATION, POSSIBLE CHEMICAL BURNS, POSSIBLE
SEVERE TISSUE DAMAGE OR DESTRUCTION, POSSIBLE BLINDNESS. SKIN: WILL
CAUSE SEVERE IRRITATION , POSSIBLE CHEMICAL BURNS WHICH MAYNOT BE
IMMEDIATELY OBVIOUS OR PAINFUL, POSSIBLE SEVERE TISSUE DAMAGE,
POSSIBLY LEADING TO PERMANENT DESTRUCTION OF SURROUNDING TISSUE.
INHALATION: MAY CAUSE SEVERE I RRITATION, POSSIBLE DAMAGE TO UPPER
RESPIRATORY TRACT. INGESTION: SEVERE IRRITATION TO GASTROINTESTINAL
TRACT, POSSIBLE TISSUE DAMAGE, TOXIC EFFECTS MAY NOT APPEAR
IMMEDIATELY.
Medical Cond Aggravated by Exposure:FLUORIDES AND ACID FLUORIDES ARE
CELLULAR POISONS. ANY TISSUE COMING IN CONTACT WITH THESE MATERIALS
WILL BE IN DANGER OF SEVERE CORROSIVE ATTACK, SEVERE DAMAGE OR
DESTRUCTION, AND NECROSIS.

First Aid:EYES: SPPED IS ESSENTIAL. IMMEDIATELY FLUSH EYES WITH LARGE
VOLUMES OF WATER FOR 5 MINUTES. THEN, NORMAL SALINE FOR 30-60
MINUTES. HOLD LIDS APART. OBTAIN IMMEDIATE MEDICAL ATTENTION. SKIN:
SPPED IS E SSENTIAL. FLUSH AFFECTED AREA WITH PLENTY OF WATER.
COVER WITH CALCIUM GLUCONATE GEL. OBTAIN MEDICAL ATTENTION AS SOON
AS POSSIBLE. INHALATION: REMOVE TO FRESH AIR. ADMINISTER OXYGEN IF
BREATHING IS D IFFICULT. GET MEDICAL ATTENTION IF IRRITATION
PERSISTS. INGESTION: DO NOT INDUCE VOMITING EXCEPT ON ADVICE OF
COMPETENT MEDICAL PERSONNEL. IF CONSCIOUS, GIVE MILK/CALCIUM
GLUCONATE SOLUTION. OBTAIN IM MEDIATE MEDICAL ATTENTION.

Flash Point:NON-FLAMMABLE
Fire Fighting Procedures:WEAR SELF-CONTAINED RESPIRATORY PROTECTION.
Unusual Fire/Explosion Hazard:CONTACT WITH REACTIVE METALS, SUCH AS
ALUMINUM, ZINC, ETC., MAY LEAD TO GENERATION OF HYDROGEN GAS IN
EXPLOSIVE AMOUNTS.

Spill Release Procedures:CONFINE SPILL. STOP LEAK AT SOURCE IF THIS CAN
BE DONE SAFELY. VENTILATE AREA. PUMP LIQUID INTO DOT-APPROVED DRUMS
FOR DISPOSAL. ABSORB REMAINING LIQUID ONTO INERT ABSORBENT AND
PLACE IN DOT-APPROVED DRUMS FOR DISPOSAL. WASH AREA WITH WATER AND
NEUTRALIZE WITH SODA ASH SOLUTION. COLLECT WASHING AND PLACE IN
DOT-APPROVED DRUMS. KEEP SPILL AND WASHINGS FROM ENTERING SEWERS OR
WATERWAYS.
Neutralizing Agent:SODA ASH SOLUTION

Handling and Storage Precautions:STORE IN DRY PROTECTED AREA. OPEN
DRUMS CAREFULLY TO AVOID SPURTING. RELIEVE ANY PRESSURE. COVER
OPENINGS TO AVOID SPURTING. CLEAN EXTERIOR AND INTERIOR BY FLUSHING
WITH WATER. COLLECT FLUSHINGS FOR D ISPOSAL. USE PROTECTIVE
EQUIPMENT FOR EYES, SKIN AND INHALATION.
Other Precautions:MIXING: CAREFULLY ADD TO WATER WHILE MIXING, TAKING
CARE TO AVOID SPLAHING. USE APPROPRIATE SAFTY EQUIPMENT TO
ELIMINATE POSSIBILITY OF SKIN OR EYE CONTACT. MAKE ADDITIONS TO
IN-USE TANKS SLOWLY AND C AUTIOUSLY.

Respiratory Protection:FOR MIST OR VAPOR CONDITIONS, A NIOSH APPROVED
RESPIRATOR FOR TOXIC MISTS OR HYDROGEN FLUORIDE IS ADVISED. IF
RESPIRATORS ARE USED, A FORMAL TRAINING AND SCREENING PROGRAM MUST
BE INITIATED. SEE 29 CF R 1910.134.
Ventilation:MAINTAIN SUFFICIENT MECHANICAL VENTILATION TO KEEP VAPOR
AND PARTICULATE CONCENTRATION BELOW TLV.
Protective Gloves:ACID RESISTANT (VITON, PVC, ETC.)
Eye Protection:CHEMICAL SAFETY GOGGLES & FACE SHIELD
Other Protective Equipment:PROTECTIVE SUIT NOT NORMALLY REQUIRED, BUT
ADVISED IF NECESSARY TO AVOID ANY POSSIBLE SKIN CONTACT OR OTHER
EXPOSURE. ACID RESISTANT BOOTS AND APRON.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING OR SMOKING. REMOVE AND LAUNDER ALL CONTAMINATED
CLOTHING. LAUNDER SEPERATELY BEFORE REUSE.
Supplemental Safety and Health
NONE

HCC:C1
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:=100.C, 212.F
B.P. Text:APPROXIMATELY.
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:20 MMHG
Vapor Density:< 1
Spec Gravity:1.33
pH:1.0
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:DARK-BROWN LIQUID; ACID ODOR
Percent Volatiles by Volume:70
Corrosion Rate:NOT PROVIDED

Stability Indicator/Materials to Avoid:YES
NOT PROVIDED
Stability Condition to Avoid:CONTACT WITH STRONG BASES, STRONG ACIDS,
REACTIVE METALS.
Hazardous Decomposition Products:ON HEATING, MAY EVOLVE CORROSIVE AND
TOXIC FUMES OF HYDROGEN FLUORIDE.

Waste Disposal Methods:1. TRANSFER TO RECLAIMING CENTER FOR RECYCLING
OR REUSE, IF POSSIBLE. 2. TRANSFER TO LICENSED HAZARDOUS WASTE
TREATMENT OR DISPOSAL SITE UNDER APPLICABLE LOCAL, STATE, AND
FEDERAL REGULATIONS. SPENT S OLUTION: DISPOSE PER 1 OR 2 OR
FLUORIDES MAY BE REMOVED BY LIME TREATMENT AND HEAVY METALS
PRECIPATE D BY PH 9.5-10.5.

Toxicological Information:NOT PROVIDED

Ecological:NOT PROVIDED

Transport Information:DOT INFORMATION: PROPER SHIPPING NAME: CORROSIVE
LIQUIDS, ACIDIC, INORGANIC, N.O.S. (FERRIC SULFATE, NITRIC ACID).
HAZARD CLASS: CORROSIVE MATERIAL. ID NUMBER: UN3264.

SARA Title III Information:NOT PROVIDED
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:THE FOLLOWING INGREDIENTS ARE NOT REQUIRED
TO BE LISTED BY 29 CFR 1910-1200, BUT, ARE LISTED IN CONFORMANCE
WITH THE 'RIGHT-TO-KNOW' LAWS OF CERTAIN STATES, INCLUDING
PENNSYLVANIA AND NEW JERSEY: WATE R (7732-18-5), FERROUS SULFATE
(7720-78-7).

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.